Name: Spin Eigenfunctions: Construction and Use (en Inglés)
Price: 585.11 PEN
Availability: InStock
Author: Pauncz, Ruben
ISBN: 9781468485288

portada Spin Eigenfunctions: Construction and Use (en Inglés)

Formato

Libro Físico

Autor

Ruben Pauncz

Editorial

Springer

Idioma

Inglés

N° páginas

370

Encuadernación

Tapa Blanda

Dimensiones

23.4 x 15.6 x 2.0 cm

Peso

0.54 kg.

ISBN13

9781468485288

Categorías

Física atómica y molecular
Física nuclear
Química física

Spin Eigenfunctions: Construction and Use (en Inglés)

Ruben Pauncz (Autor) · Springer · Tapa Blanda

Libro Nuevo

S/ 585,11

S/ 1.170,23

Ahorras: S/ 585,11

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Reseña del libro "Spin Eigenfunctions: Construction and Use (en Inglés)"

The aim of this book is to give a comprehensive treatment of the different methods for the construction of spin eigenfunctions and to show their interrelations. The ultimate goal is the construction of an antisymmetric many-electron wave function that has both spatial and spin parts and the calculation of the matrix elements of the Hamiltonian over the total wave function. The representations of the symmetric group playa central role both in the construction of spin functions and in the calculation of the matrix elements of the Hamiltonian, so this subject will be treated in detail. We shall restrict the treatment to spin-independent Hamiltonians; in this case the spin does not have a direct role in the energy expression, but the choice of spin functions influences the form of spatial functions through the antisymmetry principle; the spatial functions determine the energy of the system. We shall also present the "spin-free quantum chemistry" approach of Matsen and co-workers, in which one starts immediately with the construction of spatial functions that have the correct permutational symmetries. By presenting both the conventional and the spin-free approach, one gains a better understanding of certain aspects of the elec- tronic correlation problem. The latest advance in the calculation of the matrix elements of the Hamiltonian is the use of the representations of the unitary group, so this will be the last subject. It is a pleasant task to thank all those who helped in writing this book.